CORDIS Project
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This project focuses on creating novel metal-metal bonds, particularly involving uranium and gallium, to enhance our understanding of actinide chemistry. It aims to develop new compounds that can improve nuclear waste cleanup processes and advance the field of transition metal catalysis.
Metal-metal bonds are fundamental to generating step-changes in our knowledge because the periodic table is composed mainly of metals.
The PI has recently made a breakthrough by making the first covalent uranium-gallium bond which exhibits sigma- and pi-donation from gallium to uranium.
It is a direct model for the unknown isolobal uranium(IV)-CO unit, and is very significant to explaining why the widely used N-heterocyclic carbenes are so good at supporting transition metal catalysts and extra…
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