CORDIS Project
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This project focuses on enhancing selectivity in organic transformations using triptycene structures. By exploiting non-covalent interactions, it aims to develop iodine-based reagents that can improve reaction selectivity and efficiency in chemical synthesis.
The challenge of achieving high selectivities (chemo/regio/stereoselectivity) in organic transformations is still very high.
Selectivities are achieved through either covalent interactions involving metals or non-covalent interactions such as hydrogen bonding, halogen bonding or ion pairing involving organocatalysts or enzyme catalysts.
Triptycenes are highly promising structures due to their rigidity, internal free volume, electron rich cavities, three aromatic rings opened for π-stacking inter…
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