CORDIS Project
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The project focuses on developing new dual catalytic reactions utilizing gold and other transition metals. It aims to create innovative synthetic pathways for chemists by combining gold-catalyzed isomerization with palladium-mediated cross-coupling reactions.
We will develop new dual catalytic reactions based on the complementary reactivity of gold (I) and other transition metals.
We will perform well developed gold-catalysed isomerisation reactions and intercept carbenoid intermediates through a transmetallation event with a more redox active metal such as palladium (0).
Following this the resulting palladium carbenoid will perform a variety of cross-coupling reactions including: dimerisations, C-X insertions and C-H insertions.
This approach has no…
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