CORDIS Project
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The SINGAMBI project aims to develop a novel catalytic system that utilizes ammonia for the efficient production of alkyl amines from alkenes. By introducing a new ligand concept, it seeks to overcome the challenges of ammonia activation, promoting sustainable and waste-free chemical processes in synthetic chemistry.
The addition of ammonia to alkenes, which could produce amines in a 100% atom efficient process, has never been achieved by a molecular catalytic system and stands as a modern Holy Grail for the synthetic chemist.
Alkyl amines, a major chemical commodity, are typically accessed through stoichiometric methods, even employing toxic N1 feedstocks such as hydrogen cyanide.
The fundamental barrier to utilizing ammonia as an N1 feedstock lies in its activation, with a high N-H bond energy and a prefer…
TECHNISCHE UNIVERSITAET MUENCHEN
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