CORDIS Project
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This project investigates the optical activity of rotationally chiral molecules, which can rotate plane-polarized light. It aims to develop theoretical models for understanding this phenomenon, potentially leading to new applications in optics and materials science.
A novel effect of optical activity of highly rotationally excited non-chiral molecules has been proposed in 2004 by Bunker and Jensen (P.R.
Bunker, P.Jensen, J.
Mol.
Spec., 228 (2004) 640), where some symmetric, asymmetric, and spherical type molecules in the states can be stabilized by high rotational excitation and become rotationally chiral.
They predicted that enantiomers characterized by the so-called rotational chirality will rotate the plane-polarized light, i.e. become optically active.…
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