CORDIS Project
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This project focuses on developing new photochemical reactions involving conjugated anions and lithium compounds to create complex heterocyclic structures for medicinal chemistry. By using visible light and low temperatures, it aims to produce unique fused ring systems and biologically relevant compounds through innova…
We propose to develop new photochemical reactions of conjugated anions with lithium counterions (organolithiums and enolates) to construct functionalized, fused heterocyclic frameworks of use in medicinal chemistry development. N-Allyl/N-benzyllithiums tethered to aromatic and heteroaromatic carboxamides will be employed in dearomatizing cyclizations for the construction of partially saturated fused ring systems, generating extended lithium enolates.
Irradiation with visible light at low tempera…
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