CORDIS Project
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This project aims to develop a novel method for synthesizing chiral α-branched amines using a new photochemical system. By generating nucleophilic radicals from imine substrates, it seeks to enable new carbon-carbon bond formation techniques, enhancing synthetic methodologies in organic chemistry.
Chiral α-branched amines and their derivatives are commonplace in pharmaceuticals, agrochemicals and biologically relevant natural products.
Accordingly, the development of new synthetically powerful methods for their synthesis, and/or further functionalisation, through new carbon-carbon bond forming processes is both important and timely from academic and industrial perspectives.
Such chiral α-branched amine motifs can be accessed from electrophilic imine substrates, through direct addition of…
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