CORDIS Project
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This project develops a new method for the enantioselective arylation of carbonyl compounds using a multicatalytic platform. It utilizes visible light to drive reactions that convert abundant carboxylic acids into aryl compounds, aiming for sustainable and efficient synthesis in pharmaceuticals and agrochemicals.
The enantioselective arylation of carbonyl compounds is a powerful yet demanding transformation with broad applications in pharmaceutical and agrochemical discovery.
Current methods typically require prefunctionalised aryl reagents and costly chiral metal complexes, limiting both scope and sustainability.
This project proposes a multicatalytic platform that combines visible-light-driven Cu-catalysed decarboxylation of aryl carboxylic acids to generate aryl thianthrenium salts in situ with chiral…
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