CORDIS Project
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The MM-ZERO project focuses on advancing the chemistry of main group metals in their zero-oxidation state, aiming to develop new catalysts for hydrogenation reactions. By employing innovative ligand design and ball-milling techniques, the project seeks to create sustainable catalysts using abundant metals for efficient…
Historically, main group metal organometallics are used as stoichiometric reagents in organic synthesis.
This holds especially for highly polar s-block metal compounds like BuLi or Grignard’s.
Only since the start of this century, it has been recognized that they also make for remarkably versatile catalysts.
Parallel to these developments, the low-oxidation-state chemistry of the early main group metals emerged with the seminal isolation of first MgI complexes.
Since 2007 numerous examples have…
FRIEDRICH-ALEXANDER-UNIVERSITAET ERLANGEN-NUERNBERG
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