CORDIS Project
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This project focuses on developing new synthetic methods for creating resorcylate compounds from non-aromatic precursors. The goal is to simplify the synthesis of biologically active natural products, which have potential applications in cancer treatment and other therapeutic areas.
The applicant is seeking funding to support research on late stage biomimetic syntheses of resorcylates from readily available non-aromatic precursors. A series of diketo-dioxinones will be synthesised using mild Claisen condensation reactions and converted into the reactive intermediates triacyl-ketenes by retro-Diels Alder reactions.
These will be trapped with alcohols to directly provide the corresponding resorcylate esters and related macrocyclic lactones.
These compounds are of considerable…
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