CORDIS Project
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This project explores the unique spin interactions in molecules with unpaired electrons, focusing on chiral open-shell helices. By tuning these interactions, the project aims to understand how molecular assemblies form and their potential applications in molecular conductors and spin batteries.
Spin-delocalization in molecules containing unpaired electrons gives rise to an unusual intermolecular interaction, named as pancake bond.
This bonding interaction couples unpaired electrons between multiple pairs of atoms from each face-to-face oriented spin units, such as phenalenyl radical, and abets formation of assemblies that display large antiferromagnetic interaction in the solid state.
This phenomenon governs the potential use of such spin systems as molecular conductors, magneto-optica…
UNIVERSITAT ZURICH
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