CORDIS Project
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This project focuses on understanding the interactions in hexacyanometallate systems involving heavy elements. By combining theoretical and experimental methods, researchers aim to characterize the electronic properties and structural behavior of these materials using advanced X-ray absorption techniques.
The hexacyanometallate family is well known in transition metal chemistry because the remarkable electronic delocalization along the metal-cyano-metal bond can be tuned in order to design systems that undergo a controlled change of their physical properties.
Heavy elements, and particularly f-transition elements, have a very rich chemistry and their behaviour is still a matter of debate.
Actinide elementss are often compared to transition metal elements in the sense that their valence 5f orbital…
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