CORDIS Project
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This project explores a novel method for activating water to produce valuable compounds using a metal-free approach. It focuses on developing efficient chemical transformations through innovative radical processes, aiming to enhance hydrogenation reactions and expand the scope of organic synthesis.
Water activation, which allows the transfer of universally abundant hydrogen into value added compounds, is an important research field in modern science.
This task has been realized mainly by using transition-metal-based systems.
Herein we will use a conceptually novel mild water activation strategy which proceeds through a photocatalytic phosphine-mediated radical process.
The active species in these processes is a metal-free R3P-OH2 radical cation intermediate where both hydrogen atoms are us…
UNIVERSITAET MUENSTER
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