CORDIS Project
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This project investigates the phase behavior and properties of colloidal systems made of semi-flexible rods and discs. It aims to develop a new virial theory for phase transitions and conduct computer simulations to understand the effects of particle flexibility on these transitions.
Statistical-mechanical theories will be developed and computer simulations carried out on model colloidal systems of semi-flexible rods and discs.
The phase behaviour, structural and dynamical properties will be investigated as a function of the degree of internal particle flexibility. A more general virial theory for the isotropic-to-nematic phase transition in worm-like rods, which includes the third virial term in the excess free energy expression, will be formulated and worked out.
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