CORDIS Project
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This project explores the use of foldamers as stable supports for mimicking metalloenzyme active sites, specifically for hydrogenase models. It aims to develop new catalysts with tunable properties for applications in energy production.
The protein environment that surrounds metalloenzyme active sites imparts a wide range of effects that facilitate catalysis.
Supramolecular supports for homogenous catalysis may model a number of these effects.
However, the use of dendrimers or polymers to provide directed second coordination sphere effects is limited by their unpredictable/unstable structures.
Foldamers, based on aromatic amide units, have structures that are both highly stable and predictable in a wide range of solvents.
These…
UNIVERSITE BORDEAUX I
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