CORDIS Project
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This project focuses on understanding catalytic chain-walking reactions in nickel chemistry to create carbon-carbon bonds at previously unreactive sites. By isolating nickel intermediates, the research aims to enhance synthetic methods for drug development and functionalization.
While originally designed to control the topology of polymers, catalytic chain-walking reactions have recently offered new vistas for forging carbon-carbon bonds at previously unfunctionalized C(sp3)–H sites by formally translocating the metal catalyst throughout the alkyl side-chain of a substrate.
In particular, nickel catalysis has positioned at the forefront of this emerging field due to its modular reactivity through one- or two-electron pathways.
Nevertheless, the chain-walking process is…
FUNDACION PRIVADA INSITUTO CATALAN DE INVESTIGACION QUIMICA ICIQ
FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA
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