CORDIS Project
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This project investigates the use of water as a solvent in asymmetric catalysis, focusing on palladium-catalyzed allylation reactions. It aims to understand the mechanisms involved and improve the efficiency of these reactions in aqueous environments.
Recently, concerns over hazardous waste generated during catalytic reactions and separation of products from catalyst increasingly led to the development of systems that employ water as solvent.
An understanding of the specific mechanisms in water is required, however, for a rational optimization of processes.
Pd-catalyzed allylation has played a major role in the evolution of synthetic catalysts for asymmetric C-C bond-forming reactions in organic solvent.
However, whilst ligands are exceptiona…
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