CORDIS Project
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This project explores innovative metal-hydrogen exchange reactions using mixed-metal reagents to enhance synthetic chemistry. It focuses on developing new methodologies for regioselective reactions and synthesizing transition metal complexes, aiming to expand the scope of chemical reactions beyond traditional methods.
The metal-hydrogen exchange reaction (metallation) is one of the most fundamental synthetic tools.
Traditionally, bases such as lithium alkyls have been used for the deprotonative metallation of aromatic rings; however, their high nucleophilicity restrict their use with certain sensitive functional groups.
Professor Mulvey’s group have shown that special synergic effects can be induced by mixing an alkali metal base with certain magnesium or zinc reagents, leading to revolutionary new mixed-meta…
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